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NewsIndication of Particular Risks
R1:
Explosive when dry
R2:
Risk of explosion by shock, friction, fire or other sources of ignition
R3:
Extreme risk of explosion by shock, friction, fire or other sources of ignition
R4:
Forms very sensitive explosive metallic compounds
R5:
Heating may cause an explosion
R6:
Explosive with or without contact with air
R7:
May cause fire
R8:
Contact with combustible material may cause fire
R9:
Explosive when mixed with combustible material
R10:
Flammable
R11:
Highly Flammable
R12:
Extremely Flammable
R14:
Reacts violently with water
R15:
Contact with water liberates extremely flammable gases
R16:
Explosive when mixed with oxidizing substances
R17:
Spontaneously flammable in air
R18:
In use may form flammable/explosive vapor-air mixture
R19:
May form explosive peroxides
R20:
Harmful by inhalation
R21:
Harmful in contact with skin
R22:
Harmful if swallowed
R23:
Toxic by inhalation
R24:
Toxic in contact with skin
R25:
Toxic if swallowed
R26:
Very Toxic by inhalation
R27:
Very Toxic in contact with skin
R28:
Very Toxic if swallowed
R29:
Contact with water liberates toxic gas
R30:
Can become highly flammable in use
R31:
Contact with acids liberates toxic gas
R32:
Contact with acids liberates very toxic gas
R33:
Danger of cumulative effects
R34:
Causes burns
R35:
Causes severe burns
R36:
Irritating to the eyes
R37:
Irritating to the respiratory system
R38:
Irritating to the skin
R39:
Danger of very serious irreversible effects
R40:
Limited evidence of a carcinogenic effect
R41:
Risk of serious damage to eyes
R42:
May cause sensitization by inhalation
R43:
May cause sensitization by skin contact
R44:
Risk of explosion if heated under confinement
R45:
May cause cancer
R46:
May cause heritable genetic damage
R48:
Danger of serious damage to health by prolonged exposure
R49:
May cause cancer by inhalation
R50:
Very Toxic to aquatic organisms
R51:
Toxic to aquatic organisms
R52:
Harmful to aquatic organisms
R53:
May cause long-term adverse effects in the aquatic environment
R54:
Toxic to flora
R55:
Toxic to fauna
R56:
Toxic to soil organisms
R57:
Toxic to bees
R58:
May cause long-term adverse effects in the environment
R59:
Dangerous for the ozone layer
R60:
May impair fertility
R61:
May cause harm to the unborn child
R62:
Possible risk of impaired fertility
R63:
Possible risk of harm to the unborn child
R64:
May cause harm to breast-fed babies
R65:
Harmful: May cause lung damage if swallowed
R66:
Repeated exposure may cause skin dryness or cracking
R67:
Vapors may cause drowsiness and dizziness
R68:
Possible risk of irreversible effects
Combination of Particular Risks
R14/15:
Reacts violently with water, liberating extremely flammable gases
R15/29:
Contact with water liberates toxic, extremely flammable gas
R20/21:
Harmful by inhalation and in contact with skin
R20/21/22:
Harmful by inhalation, in contact with skin and if swallowed
R20/22:
Harmful by inhalation and if swallowed
R21/22:
Harmful in contact with skin and if swallowed
R23/24:
Toxic by inhalation and in contact with skin
R23/24/25:
Toxic by inhalation, in contact with skin and if swallowed
R23/25:
Toxic by inhalation and if swallowed
R24/25:
Toxic in contact with skin and if swallowed
R26/27:
Very Toxic by inhalation and in contact with skin
R26/27/28:
Very Toxic by inhalation, in contact with skin and if swallowed
R26/28:
Very Toxic by inhalation and if swallowed
R27/28:
Very Toxic in contact with skin and if swallowed
R36/37:
Irritating to eyes and respiratory system
R36/37/38:
Irritating to eyes, respiratory system and skin
R36/38:
Irritating to eyes and skin
R37/38:
Irritating to respiratory system and skin
R39/23:
Toxic: danger of very serious irreversible effects through inhalation
R39/23/24:
Toxic: danger of very serious irreversible effects through inhalation in contact with skin
R39/23/24/25:
Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
R39/23/25:
Toxic: danger of very serious irreversible effects through inhalation and if swallowed
R39/24:
Toxic: danger of very serious irreversible effects in contact with skin
R39/24/25:
Toxic: danger of very serious irreversible effects in contact with skin and if swallowed
R39/25:
Toxic: danger of very serious irreversible effects if swallowed
R39/26:
Very Toxic: danger of very serious irreversible effects through inhalation
R39/26/27:
Very Toxic: danger of very serious irreversible effects through inhalation and in contact with skin
R39/26/27/28:
Very Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
R39/26/28:
Very Toxic: danger of very serious irreversible effects through inhalation and if swallowed
R39/27:
Very Toxic: danger of very serious irreversible effects in contact with skin
R39/27/28:
Very Toxic: danger of very serious irreversible effects in contact with skin and if swallowed
R39/28:
Very Toxic: danger of very serious irreversible effects if swallowed
R42/43:
May cause sensitization by inhalation and skin contact
R48/20:
Harmful: danger of serious damage to health by prolonged exposure through inhalation
R48/20/21:
Harmful: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin
R48/20/21/22:
Harmful: danger of serious damage to health by prolonged exposure through inhalation, and in contact with skin and if swallowed
R48/20/22:
Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed
R48/21:
Harmful: danger of serious damage to health by prolonged exposure in contact with skin
R48/21/22:
Harmful: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed
R48/22:
Harmful: danger of serious damage to health by prolonged exposure if swallowed
R48/23:
Toxic: danger of serious damage to health by prolonged exposure through inhalation
R48/23/24:
Toxic: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin
R48/23/24/25:
Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed
R48/23/25:
Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed
R48/24:
Toxic: danger of serious damage to health by prolonged exposure in contact with skin
R48/24/25:
Toxic: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed
R48/25:
Toxic: danger of serious damage to health by prolonged exposure if swallowed
R50/53:
Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R51/53:
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R52/53:
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R68/20:
Harmful: possible risk of irreversible effects through inhalation
R68/20/21:
Harmful: possible risk of irreversible effects through inhalation and in contact with skin
R68/20/21/22:
Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed
R68/20/22:
Harmful: possible risk of irreversible effects through inhalation and if swallowed
R68/22:
Harmful: possible risk of irreversible effects if swallowed
R68/21:
Harmful: possible risk of irreversible effects in contact with skin
R68/21/22:
Harmful: possible risk of irreversible effects in contact with skin and if swallowed
R68/22:
Harmful: possible risk of irreversible effects if swallowed
Chemical Safety Phrases
Combination of Safety Precautions
S1:
Keep locked up
S2:
Keep out of the reach of children
S3:
Keep in a cool place
S4:
Keep away from living quarters
S5:
Keep contents under ... (appropriate liquid to be specified by the manufacturer)
S6:
Keep under ... (inert gas to be specified by the manufacturer)
7:
Keep container tightly closed
S8:
Keep container dry
S9:
Keep container in a well-ventilated place
S12:
Do not keep the container sealed
S13:
Keep away from food, drink and animal feeding stuffs
S14:
Keep away from ... (incompatible materials to be indicated by the manufacturer)
S15:
Keep away from heat
S16:
Keep away from sources of ignition - No smoking
S17:
Keep away from combustible material
S18:
Handle and open container with care
S20:
When using, do not eat or drink
S21:
When using, do not smoke
S22:
Do not breathe dust
S23:
Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer)
S24:
Avoid contact with skin
S25:
Avoid contact with eyes
S26:
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S27:
Take off immediately all contaminated clothing
S28:
After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer)
S29:
Do not empty into drains
S30:
VNever add water to this product
S33:
Take precautionary measures against static discharges
S35:
This material and its container must be disposed of in a safe way
S36:
Wear suitable protective clothing
S37:
Wear suitable gloves
S38:
In case of insufficient ventilation, wear suitable respiratory equipment
S39:
Wear eye/face protection
S40:
To clean the floor and all objects contaminated by this material use ... (to be specified by the manufacturer)
S41:
In case of fire and/or explosion do not breathe fumes
S42:
During fumigation/spraying wear suitable respiratory equipment (appropriate wording to be specified)
S43:
In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)
S45:
In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
S46:
If swallowed, seek medical advice immediately and show this container or label
S47:
Keep at temperature not exceeding ... E C (to be specified by the manufacturer)
S48:
Keep wetted with ... (appropriate material to be specified by the manufacturer)
S49:
Keep only in the original container
S50:
Do not mix with ... (to be specified by the manufacturer)
S51:
Use only in well-ventilated areas
S52:
Not recommended for interior use on large surface areas
S53:
Avoid exposure - obtain special instruction before use
S56:
Dispose of this material and its container to hazardous or special waste collection point
S57:
Use appropriate container to avoid environmental contamination
S59:
Refer to manufacturer/supplier for information on recovery/recycling
S60:
This material and/or its container must be disposed of as hazardous waste
S61:
Avoid release to the environment. Refer to special instructions safety data sheet
S62:
If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label
S63:
In case of accident by inhalation, remove casualty to fresh air and keep at rest
S64:
If swallowed, rinse mouth with water (only if the person is conscious)
Indication of Safety Precautions
S1/2:
Keep locked up and out of the reach of children
S3/7:
Keep container tightly closed in a cool place
S3/9/14:
Keep in a cool well-ventilated place away from ... (incompatible materials to be indicated by manufacturer)
S3/9/14/49:
Keep only in the original container in a cool well-ventilated place away from ... (incompatible materials to be indicated by manufacturer)
S3/9/49:
Keep only in the original container in a cool well-ventilated place
S3/14:
Keep in a cool place away from ... (incompatible materials to be indicated by the manufacturer)
S7/8:
Keep container tightly closed and dry
S7/9:
Keep container tightly closed and at a temperature not exceeding ... °C (to be specified by manufacturer)
S20/21:
When using, do not eat, drink or smoke
S24/25:
Avoid contact with skin and eyes
S27/28:
After contact with skin, take off immediately all contaminated clothing and wash imediately with plenty of.... (to be specified by the manufacturer)
S29/35:
Do not empty into drains, dispose of this container and it's material in a safe way
S29/56:
Do not empty into drains, dispose of this material and its container to hazardous or special waste-collection point
S36/37:
Wear suitable protective clothing and gloves
S36/37/39:
Wear suitable protective clothing, gloves and eye/face protection
S36/39:
Wear suitable protective clothing and eye/face protection
S37/39:
Wear suitable gloves and eye/face protection
S47/49:
Keep only in the original container at temperature not exceeding ... °C (to be specified by manufacturer)
FLUKA BRAND F CODES
1. F 1 Sensitive to air and humidity.
2. F 2 Sensitive to air and CO2.
3. F 3 Hygroscopic.
4. F 4 Do not heat over …°C.
1 = 10 °C
2 = 20 °C
3 = 30 °C
4 = 40 °C
5 = 50 °C
6 = 60 °C
7 = 70 °C
8 = 80 °C
9 = 90 °C
10 = 100 °C
11 = 110 °C
12 = 120 °C
13 = 130 °C
14 = 140 °C
15 = 150 °C
F 5 Dry material may explode.
F 6 Reacts with acids.
F 7 Keep under CO2.
F 8 Photosensitive.
F 9 Keep under nitrogen.
F 10 Keep under argon.
F 11 Keep under inert gas.
F 12 Shake before use.
F 13 Malodorous.
F 14 Carefully observe warning label.
F 15 Limited shelf life.
F 16 Decomposes easily.
F 17 May decompose by explosion.
F 18 Must be handled by instructed people only.
F 19 Lachrymator.
F 20 Not to be swallowed.
F 21 Sensitive to humidity.
F 22 Keep dust-free in the dark.
F 23 Sensitive to air.
F 24 Spontaneously flammable with alcohol.
F 25 Keep under CO.
F 26 Before distillation test for absence of peroxides.
F 27 Cool before opening.
F 28 May become cloudy (Polyformaldehyde).
F 29 Spontaneously flammable when dry.
F 30 Sediment unavoidable.
F 31 Do not puncture.
F 32 Avoid contact with heavy metal salts especially iron salts.
F 33 Causes fall in blood pressure.
F 34 Sensitive to CO2.
F 35 Narcotic effects.
F 36 Extremely sensitive to air.
PICTOGRAMS AND HAZARD CODES
 B Biohazard |
 CCorrosive |
 EExplosive |
 F Highly Flammable F+
Extremely Flammable |
 Xn Harmful Xi
Irritant |
 NDangerous for the environment |
O
Oxidizing |
R
Radioactive |
T |
